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Dimer Involvement and Origin of Crossover in Nickel-Catalyzed Aldehyde–Alkyne Reductive Couplings

[Image: see text] The mechanism of nickel(0)-catalyzed reductive coupling of aldehydes and alkynes has been studied. Extensive double-labeling crossover studies have been conducted. While previous studies illustrated that phosphine- and N-heterocyclic carbene-derived catalysts exhibited differing be...

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Detalles Bibliográficos
Autores principales: Haynes , M. Taylor, Liu, Peng, Baxter, Ryan D., Nett, Alex J., Houk, K. N., Montgomery, John
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277774/
https://www.ncbi.nlm.nih.gov/pubmed/25401337
http://dx.doi.org/10.1021/ja508909u