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Development of Chiral Bis-hydrazone Ligands for the Enantioselective Cross-Coupling Reactions of Aryldimethylsilanolates

[Image: see text] A palladium-catalyzed, enantioselective, aryl–aryl cross-coupling reaction using 1-naphthyldimethylsilanolates and chiral bis-hydrazone ligands has been developed. A family of glyoxal bis-hydrazone ligands containing various 2,5-diarylpyrrolidine groups was prepared to evaluate the...

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Detalles Bibliográficos
Autores principales: Denmark, Scott E., Chang, Wen-Tau T., Houk, K. N., Liu, Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4285162/
https://www.ncbi.nlm.nih.gov/pubmed/25494058
http://dx.doi.org/10.1021/jo502388r