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Multiple light-induced NO linkage isomers in the dinitrosyl complex [RuCl(NO)(2)(PPh(3))(2)]BF(4) unravelled by photocrystallographic and IR analysis

Multiple light-induced reversible metastable NO linkage isomers (PLIs) have been detected in the dinitrosyl compound [RuCl(NO)(2)(PPh(3))(2)]BF(4) by a combination of photocrystallographic and IR analysis. The IR signature of three PLI states has been clearly identified, with estimated populations o...

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Detalles Bibliográficos
Autores principales: Casaretto, Nicolas, Pillet, Sebastien, Bendeif, El Eulmi, Schaniel, Dominik, Gallien, Anna K. E., Klüfers, Peter, Woike, Theo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4285879/
https://www.ncbi.nlm.nih.gov/pubmed/25610626
http://dx.doi.org/10.1107/S2052252514023598