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Investigations of the Effect of the Non-Manganese Metal in Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium
[Image: see text] We report the syntheses and electrochemical properties of nine new clusters ([LLnMn(IV)(3)O(4)(OAc)(3)(DMF)(n)](+) (Ln = La(3+), Ce(3+), Nd(3+), Eu(3+), Gd(3+), Tb(3+), Dy(3+), Yb(3+), and Lu(3+), n = 2 or 3)) supported by a ligand (L(3–)) based on a 1,3,5-triarylbenzene motif appe...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4286168/ https://www.ncbi.nlm.nih.gov/pubmed/25521310 http://dx.doi.org/10.1021/ic5015219 |