Nonracemic Allylic Boronates through Enantiotopic-Group-Selective Cross-Coupling of Geminal Bis(boronates) and Vinyl Halides

[Image: see text] Under the influence of a chiral palladium catalyst, 1,1-bis(pinacolboronate) esters undergo asymmetric cross-coupling with bromoalkenes to generate nonracemic allyl boronates with high levels of enantioselectivity. The so-formed allyl boronates may be oxidized with hydrogen peroxid...

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Detalles Bibliográficos
Autores principales: Potter, Bowman, Szymaniak, Adam A., Edelstein, Emma K., Morken, James P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4291770/
https://www.ncbi.nlm.nih.gov/pubmed/25482206
http://dx.doi.org/10.1021/ja510266x

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4291770/
https://www.ncbi.nlm.nih.gov/pubmed/25482206
http://dx.doi.org/10.1021/ja510266x

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