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Enantioselective Synthesis of (−)-Maoecrystal V by Enantiodetermining C–H Functionalization

[Image: see text] The evolution of a program directed at the enantioselective total synthesis of maoecrystal V, a highly modified ent-kauranoid, is described. An early stage chiral auxiliary-directed asymmetric C–H functionalization for the construction of a key benzofuran intermediate enabled the f...

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Detalles Bibliográficos
Autores principales: Lu, Ping, Mailyan, Artur, Gu, Zhenhua, Guptill, David M., Wang, Hengbin, Davies, Huw M. L., Zakarian, Armen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4291805/
https://www.ncbi.nlm.nih.gov/pubmed/25409033
http://dx.doi.org/10.1021/ja510573v