Cargando…
Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8π Insertion
[Image: see text] A Ni/N-heterocyclic carbene catalyst couples diynes to the C(α)–C(β) double bond of tropone, a type of reaction that is unprecedented for metal-catalyzed cycloadditions with aromatic tropone. Many different diynes were efficiently coupled to afford [5–6–7] fused tricyclic products,...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4291811/ https://www.ncbi.nlm.nih.gov/pubmed/25416006 http://dx.doi.org/10.1021/ja5105206 |