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Rationale for the sluggish oxidative addition of aryl halides to Au(i)
The oxidative addition of C(sp(2))–Br or C(sp(2))–I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is ki...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4295554/ https://www.ncbi.nlm.nih.gov/pubmed/24382586 http://dx.doi.org/10.1039/c3cc48914k |