Rationale for the sluggish oxidative addition of aryl halides to Au(i)

The oxidative addition of C(sp(2))–Br or C(sp(2))–I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is ki...

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Autores principales: Livendahl, Madeleine, Goehry, Charles, Maseras, Feliu, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4295554/
https://www.ncbi.nlm.nih.gov/pubmed/24382586
http://dx.doi.org/10.1039/c3cc48914k
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author Livendahl, Madeleine
Goehry, Charles
Maseras, Feliu
Echavarren, Antonio M.
author_facet Livendahl, Madeleine
Goehry, Charles
Maseras, Feliu
Echavarren, Antonio M.
author_sort Livendahl, Madeleine
collection PubMed
description The oxidative addition of C(sp(2))–Br or C(sp(2))–I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish.
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spelling pubmed-42955542015-01-26 Rationale for the sluggish oxidative addition of aryl halides to Au(i) Livendahl, Madeleine Goehry, Charles Maseras, Feliu Echavarren, Antonio M. Chem Commun (Camb) Chemistry The oxidative addition of C(sp(2))–Br or C(sp(2))–I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. Royal Society of Chemistry 2014-01-16 2014-02-14 /pmc/articles/PMC4295554/ /pubmed/24382586 http://dx.doi.org/10.1039/c3cc48914k Text en This journal is © The Royal Society of Chemistry 2014 http://creativecommons.org/licenses/by-nc/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial 3.0 Unported License (http://creativecommons.org/licenses/by-nc/3.0/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Livendahl, Madeleine
Goehry, Charles
Maseras, Feliu
Echavarren, Antonio M.
Rationale for the sluggish oxidative addition of aryl halides to Au(i)
title Rationale for the sluggish oxidative addition of aryl halides to Au(i)
title_full Rationale for the sluggish oxidative addition of aryl halides to Au(i)
title_fullStr Rationale for the sluggish oxidative addition of aryl halides to Au(i)
title_full_unstemmed Rationale for the sluggish oxidative addition of aryl halides to Au(i)
title_short Rationale for the sluggish oxidative addition of aryl halides to Au(i)
title_sort rationale for the sluggish oxidative addition of aryl halides to au(i)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4295554/
https://www.ncbi.nlm.nih.gov/pubmed/24382586
http://dx.doi.org/10.1039/c3cc48914k
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AT maserasfeliu rationaleforthesluggishoxidativeadditionofarylhalidestoaui
AT echavarrenantoniom rationaleforthesluggishoxidativeadditionofarylhalidestoaui

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