The reaction of an iridium PNP complex with parahydrogen facilitates polarisation transfer without chemical change

The short lived pincer complex [(C(5)H(3)N(CH(2)P((t)Bu)(2))(2))Ir(H)(2)(py)]BF(4) is shown to be active for signal amplification by reversible exchange. This catalyst formulation enables the efficient transfer of polarization from parahydrogen to be placed into just a single molecule of the hyperpo...

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Detalles Bibliográficos
Autores principales: Holmes, Arthur J., Rayner, Peter J., Cowley, Michael J., Green, Gary G. R., Whitwood, Adrian C., Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4295814/
https://www.ncbi.nlm.nih.gov/pubmed/25410259
http://dx.doi.org/10.1039/c4dt03088e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4295814/
https://www.ncbi.nlm.nih.gov/pubmed/25410259
http://dx.doi.org/10.1039/c4dt03088e

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