Gold(I) as an Artificial Cyclase: Short Stereodivergent Syntheses of (−)-Epiglobulol and (−)-4β,7α- and (−)-4α,7α-Aromadendranediols**

Three natural aromadendrane sesquiterpenes, (−)-epiglobulol, (−)-4β,7α-aromadendranediol, and (−)-4α,7α-aromadendranediol, have been synthesized in only seven steps in 12, 15, and 17 % overall yields, respectively, from (E,E)-farnesol by a stereodivergent gold(I)-catalyzed cascade reaction which for...

Descripción completa

Detalles Bibliográficos
Autores principales: Carreras, Javier, Livendahl, Madeleine, McGonigal, Paul R, Echavarren, Antonio M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4298797/
https://www.ncbi.nlm.nih.gov/pubmed/24692360
http://dx.doi.org/10.1002/anie.201402044

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4298797/
https://www.ncbi.nlm.nih.gov/pubmed/24692360
http://dx.doi.org/10.1002/anie.201402044

Ejemplares similares