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Synthesis and Characterization of Mononuclear, Pseudotetrahedral Cobalt(III) Compounds

[Image: see text] The preparation and characterization of two mononuclear cobalt(III) tropocoronand complexes, [Co(TC-5,5)](BF(4)) and [Co(TC-6,6)](BPh(4)), are reported. The cobalt(III) centers exist in rare pseudotetrahedral conformations, with twist angles of 65° and 74° for the [Co(TC-5,5](+) an...

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Detalles Bibliográficos
Autores principales: Kozhukh, Julia, Minier, Mikael A., Lippard, Stephen J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4303325/
https://www.ncbi.nlm.nih.gov/pubmed/25531129
http://dx.doi.org/10.1021/ic5009279