Flexibility transition and guest-driven reconstruction in a ferroelastic metal–organic framework

The metal–organic framework copper(i) tricyanomethanide, Cu(tcm), undergoes a ferroelastic transition on cooling below T(f) = 240 K. Thermal expansion measurements reveal an order-of-magnitude variation in framework flexibility across T(f). The low-temperature phase α-Cu(tcm) exhibits colossal posit...

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Detalles Bibliográficos
Autores principales: Hunt, Sarah J., Cliffe, Matthew J., Hill, Joshua A., Cairns, Andrew B., Funnell, Nicholas P., Goodwin, Andrew L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4304274/
https://www.ncbi.nlm.nih.gov/pubmed/25632268
http://dx.doi.org/10.1039/c4ce01572j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4304274/
https://www.ncbi.nlm.nih.gov/pubmed/25632268
http://dx.doi.org/10.1039/c4ce01572j

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