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Flexibility transition and guest-driven reconstruction in a ferroelastic metal–organic framework

The metal–organic framework copper(i) tricyanomethanide, Cu(tcm), undergoes a ferroelastic transition on cooling below T(f) = 240 K. Thermal expansion measurements reveal an order-of-magnitude variation in framework flexibility across T(f). The low-temperature phase α-Cu(tcm) exhibits colossal posit...

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Detalles Bibliográficos
Autores principales:	Hunt, Sarah J., Cliffe, Matthew J., Hill, Joshua A., Cairns, Andrew B., Funnell, Nicholas P., Goodwin, Andrew L.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2014
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4304274/ https://www.ncbi.nlm.nih.gov/pubmed/25632268 http://dx.doi.org/10.1039/c4ce01572j

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