Biomimetic Kinetic Resolution: Highly Enantio- and Diastereoselective Transfer Hydrogenation of Aglain Ketones To Access Flavagline Natural Products

[Image: see text] We have previously reported asymmetric syntheses and absolute configuration assignments of the aglains (+)-ponapensin and (+)-elliptifoline and proposed a biosynthetic kinetic resolution process to produce enantiomeric rocaglamides and aglains. Herein, we report a biomimetic approa...

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Detalles Bibliográficos
Autores principales: Stone, Steven D., Lajkiewicz, Neil J., Whitesell, Luke, Hilmy, Ahmed, Porco, John A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4304436/
https://www.ncbi.nlm.nih.gov/pubmed/25514979
http://dx.doi.org/10.1021/ja511728b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4304436/
https://www.ncbi.nlm.nih.gov/pubmed/25514979
http://dx.doi.org/10.1021/ja511728b

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