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Chemoselective Activation of sp(3) vs sp(2) C–H Bonds with Pd(II)
[Image: see text] The first selective coupling of a carbon nucleophile with methyl, ethyl, propyl, and butyl arenes in the absence of a directing group is described. Pd(OAc)(2) double C–H activation displays remarkable selectivity for the terminal methyl sites in alkyl arenes, rather than the more c...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4304446/ https://www.ncbi.nlm.nih.gov/pubmed/25423164 http://dx.doi.org/10.1021/ja5093166 |