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Synthesis of Highly Functionalized Tri- and Tetrasubstituted Alkenes via Pd-Catalyzed 1,2-Hydrovinylation of Terminal 1,3-Dienes

[Image: see text] An efficient method for the construction of Csp(2)–Csp(3) bond in a regio- and stereoselective fashion involving 1,3-terminal dienes, enol triflates/nonaflates, and sodium formate under Pd(0)-catalysis is described. The three component assembly allows trapping of a π-allyl intermed...

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Detalles Bibliográficos
Autores principales: Saini, Vaneet, O’Dair, Mark, Sigman, Matthew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4308737/
https://www.ncbi.nlm.nih.gov/pubmed/25555197
http://dx.doi.org/10.1021/ja511640g