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A facile synthesis of functionalized 7,8-diaza[5]helicenes through an oxidative ring-closure of 1,1’-binaphthalene-2,2’-diamines (BINAMs)

A facile and moderately functional-group-tolerant synthetic method for the preparation of 7,8-diaza[5]helicenes has been developed. It comprises of an oxidative ring-closing process of 1,1’-binaphthalene-2,2’-diamine (BINAM) derivatives with a chlorine-containing oxidant (t-BuOCl) in the presence of...

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Detalles Bibliográficos
Autores principales: Takeda, Youhei, Okazaki, Masato, Maruoka, Yoshiaki, Minakata, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311764/
https://www.ncbi.nlm.nih.gov/pubmed/25670986
http://dx.doi.org/10.3762/bjoc.11.2