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Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts
[Image: see text] Both alkylarylalkynes and diarylalkynes 1 are converted into the α-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4316994/ https://www.ncbi.nlm.nih.gov/pubmed/24684513 http://dx.doi.org/10.1021/ol500592m |