Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts

[Image: see text] Both alkylarylalkynes and diarylalkynes 1 are converted into the α-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do...

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Detalles Bibliográficos
Autores principales: Jung, Michael E., Deng, Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4316994/
https://www.ncbi.nlm.nih.gov/pubmed/24684513
http://dx.doi.org/10.1021/ol500592m
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author Jung, Michael E.
Deng, Gang
author_facet Jung, Michael E.
Deng, Gang
author_sort Jung, Michael E.
collection PubMed
description [Image: see text] Both alkylarylalkynes and diarylalkynes 1 are converted into the α-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do not provide the diketone product. A possible mechanism is proposed.
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spelling pubmed-43169942015-04-01 Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts Jung, Michael E. Deng, Gang Org Lett [Image: see text] Both alkylarylalkynes and diarylalkynes 1 are converted into the α-diketones 2 in good yield by the use of mercuric salts, e.g., mercuric nitrate hydrate or mercuric triflate, in the presence of water. Other mercuric salts, e.g., sulfate, chloride, acetate, or trifluoroacetate, do not provide the diketone product. A possible mechanism is proposed. American Chemical Society 2014-04-01 2014-04-18 /pmc/articles/PMC4316994/ /pubmed/24684513 http://dx.doi.org/10.1021/ol500592m Text en Copyright © 2014 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Jung, Michael E.
Deng, Gang
Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts
title Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts
title_full Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts
title_fullStr Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts
title_full_unstemmed Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts
title_short Synthesis of α-Diketones from Alkylaryl- and Diarylalkynes Using Mercuric Salts
title_sort synthesis of α-diketones from alkylaryl- and diarylalkynes using mercuric salts
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4316994/
https://www.ncbi.nlm.nih.gov/pubmed/24684513
http://dx.doi.org/10.1021/ol500592m
work_keys_str_mv AT jungmichaele synthesisofadiketonesfromalkylarylanddiarylalkynesusingmercuricsalts
AT denggang synthesisofadiketonesfromalkylarylanddiarylalkynesusingmercuricsalts

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