Dramatic Influence of an Anionic Donor on the Oxygen-Atom Transfer Reactivity of a Mn(V)–Oxo Complex

Addition of an anionic donor to an Mn(V)(O) porphyrinoid complex causes a dramatic increase in 2-electron oxygen-atom-transfer (OAT) chemistry. The 6-coordinate [Mn(V)(O)(TBP(8)Cz)(CN)](−) was generated from addition of Bu(4)N(+)CN(−) to the 5-coordinate Mn(V)(O) precursor. The cyanide-ligated compl...

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Detalles Bibliográficos
Autores principales: Neu, Heather M, Quesne, Matthew G, Yang, Tzuhsiung, Prokop-Prigge, Katharine A, Lancaster, Kyle M, Donohoe, James, DeBeer, Serena, de Visser, Sam P, Goldberg, David P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4321347/
https://www.ncbi.nlm.nih.gov/pubmed/25256417
http://dx.doi.org/10.1002/chem.201404349

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4321347/
https://www.ncbi.nlm.nih.gov/pubmed/25256417
http://dx.doi.org/10.1002/chem.201404349

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