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Dramatic Influence of an Anionic Donor on the Oxygen-Atom Transfer Reactivity of a Mn(V)–Oxo Complex
Addition of an anionic donor to an Mn(V)(O) porphyrinoid complex causes a dramatic increase in 2-electron oxygen-atom-transfer (OAT) chemistry. The 6-coordinate [Mn(V)(O)(TBP(8)Cz)(CN)](−) was generated from addition of Bu(4)N(+)CN(−) to the 5-coordinate Mn(V)(O) precursor. The cyanide-ligated compl...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
WILEY-VCH Verlag
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4321347/ https://www.ncbi.nlm.nih.gov/pubmed/25256417 http://dx.doi.org/10.1002/chem.201404349 |