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Reversible monolayer-to-crystalline phase transition in amphiphilic silsesquioxane at the air-water interface

We report on the counter intuitive reversible crystallisation of two-dimensional monolayer of Trisilanolisobutyl Polyhedral Oligomeric SilSesquioxane (TBPOSS) on water surface using synchrotron x-ray scattering measurements. Amphiphilic TBPOSS form rugged monolayers and Grazing Incidence X-ray Scatt...

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Detalles Bibliográficos
Autores principales: Banerjee, R., Sanyal, M. K., Bera, M. K., Gibaud, A., Lin, B., Meron, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4330523/
https://www.ncbi.nlm.nih.gov/pubmed/25687953
http://dx.doi.org/10.1038/srep08497