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Unveiling the Dependence of Glass Transitions on Mixing Thermodynamics in Miscible Systems
The dependence of the glass transition in mixtures on mixing thermodynamics is examined by focusing on enthalpy of mixing, ΔH(mix) with the change in sign (positive vs. negative) and magnitude (small vs. large). The effects of positive and negative ΔH(mix) are demonstrated based on two isomeric syst...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4330544/ https://www.ncbi.nlm.nih.gov/pubmed/25686751 http://dx.doi.org/10.1038/srep08500 |