Tuning the Reactivity of Fe(V)(O) toward C–H Bonds at Room Temperature: Effect of Water

[Image: see text] The presence of an Fe(V)(O) species has been postulated as the active intermediate for the oxidation of both C–H and C=C bonds in the Rieske dioxygenase family of enzymes. Understanding the reactivity of these high valent iron–oxo intermediates, especially in an aqueous medium, wou...

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Detalles Bibliográficos
Autores principales: Singh, Kundan K., Tiwari, Mrityunjay k., Ghosh, Munmun, Panda, Chakadola, Weitz, Andrew, Hendrich, Michael P., Dhar, Basab B., Vanka, Kumar, Sen Gupta, Sayam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4332042/
https://www.ncbi.nlm.nih.gov/pubmed/25594114
http://dx.doi.org/10.1021/ic502535f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4332042/
https://www.ncbi.nlm.nih.gov/pubmed/25594114
http://dx.doi.org/10.1021/ic502535f

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