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Experimental Lineage and Functional Analysis of a Remotely Directed Peptide Epoxidation Catalyst
[Image: see text] We describe mechanistic investigations of a catalyst (1) that leads to selective epoxidation of farnesol at the 6,7-position, remote from the hydroxyl directing group. The experimental lineage of peptide 1 and a number of resin-bound peptide analogues were examined to reveal the im...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4333582/ https://www.ncbi.nlm.nih.gov/pubmed/24690108 http://dx.doi.org/10.1021/ja410567a |