Cargando…
Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis
[Image: see text] Direct β-alkylation of saturated aldehydes has been accomplished by synergistically combining photoredox catalysis and organocatalysis. Photon-induced enamine oxidation provides an activated β-enaminyl radical intermediate, which readily combines with a wide range of Michael accept...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4333594/ https://www.ncbi.nlm.nih.gov/pubmed/24754456 http://dx.doi.org/10.1021/ja502639e |