Redox-Neutral α-Oxygenation of Amines: Reaction Development and Elucidation of the Mechanism

[Image: see text] Cyclic secondary amines and 2-hydroxybenzaldehydes or related ketones react to furnish benzo[e][1,3]oxazine structures in generally good yields. This overall redox-neutral amine α-C–H functionalization features a combined reductive N-alkylation/oxidative α-functionalization and is...

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Detalles Bibliográficos
Autores principales: Richers, Matthew T., Breugst, Martin, Platonova, Alena Yu., Ullrich, Anja, Dieckmann, Arne, Houk, K. N., Seidel, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4333595/
https://www.ncbi.nlm.nih.gov/pubmed/24689802
http://dx.doi.org/10.1021/ja501988b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4333595/
https://www.ncbi.nlm.nih.gov/pubmed/24689802
http://dx.doi.org/10.1021/ja501988b

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