Ligand-Sensitive But Not Ligand-Diagnostic: Evaluating Cr Valence-to-Core X-ray Emission Spectroscopy as a Probe of Inner-Sphere Coordination

[Image: see text] This paper explores the strengths and limitations of valence-to-core X-ray emission spectroscopy (V2C XES) as a probe of coordination environments. A library was assembled from spectra obtained for 12 diverse Cr complexes and used to calibrate density functional theory (DFT) calcul...

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Detalles Bibliográficos
Autores principales: MacMillan, Samantha N., Walroth, Richard C., Perry, Demetra M., Morsing, Thorbjørn J., Lancaster, Kyle M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4335811/
https://www.ncbi.nlm.nih.gov/pubmed/25496512
http://dx.doi.org/10.1021/ic502152r

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4335811/
https://www.ncbi.nlm.nih.gov/pubmed/25496512
http://dx.doi.org/10.1021/ic502152r

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