Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones

An asymmetric palladium-catalyzed conjugate addition reaction of arylboronic acids to enone substrates was investigated mechanistically. Desorption electrospray ionization coupled to mass spectrometry was used to identify intermediates of the catalytic cycle and delineate differences in substrate re...

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Detalles Bibliográficos
Autores principales: Boeser, Cornelia L., Holder, Jeffrey C., Taylor, Buck L. H., Houk, K. N., Stoltz, Brian M., Zare, Richard N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4338963/
https://www.ncbi.nlm.nih.gov/pubmed/25729560
http://dx.doi.org/10.1039/c4sc03337j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4338963/
https://www.ncbi.nlm.nih.gov/pubmed/25729560
http://dx.doi.org/10.1039/c4sc03337j

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