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Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins

The Z-selective cross metathesis of allylic-substituted olefins is explored with recently developed ruthenium-based metathesis catalysts. The reaction proceeds with excellent stereoselectivity for the Z-isomer (typically >95%) and yields of up to 88% for a variety of allylic substituents. This in...

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Detalles Bibliográficos
Autores principales: Quigley, Brendan L., Grubbs, Robert H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4339074/
https://www.ncbi.nlm.nih.gov/pubmed/25722847
http://dx.doi.org/10.1039/c3sc52806e