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Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins
The Z-selective cross metathesis of allylic-substituted olefins is explored with recently developed ruthenium-based metathesis catalysts. The reaction proceeds with excellent stereoselectivity for the Z-isomer (typically >95%) and yields of up to 88% for a variety of allylic substituents. This in...
Autores principales: | Quigley, Brendan L., Grubbs, Robert H. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4339074/ https://www.ncbi.nlm.nih.gov/pubmed/25722847 http://dx.doi.org/10.1039/c3sc52806e |
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