Hydrogen-Borrowing and Interrupted-Hydrogen-Borrowing Reactions of Ketones and Methanol Catalyzed by Iridium**

Reported herein is the use of catalytic [{Ir(cod)Cl}(2)] to facilitate hydrogen-borrowing reactions of ketone enolates with methanol at 65 °C. An oxygen atmosphere accelerates the process, and when combined with the use of a bulky monodentate phosphine ligand, interrupts the catalytic cycle by preve...

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Detalles Bibliográficos
Autores principales: Shen, Di, Poole, Darren L, Shotton, Camilla C, Kornahrens, Anne F, Healy, Mark P, Donohoe, Timothy J
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4344817/
https://www.ncbi.nlm.nih.gov/pubmed/25491653
http://dx.doi.org/10.1002/anie.201410391

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4344817/
https://www.ncbi.nlm.nih.gov/pubmed/25491653
http://dx.doi.org/10.1002/anie.201410391

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