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Crystal structure of [1-(2,6-diisopropylphenyl)-2,4-bis(dimethylamino)-5-trimethylsilyl-1,3,5-triazapentadienyl-κ(2) N (1),N (5)](triphenylphosphane-κP)copper(I)
The title complex, [Cu(C(21)H(38)N(5)Si)(C(18)H(15)P)], was obtained from the one-pot reaction between (Dipp)N(Li)SiMe(3) (Dipp = 2,6-diisopropylphenyl), Me(2)NCN, CuCl and PPh(3). The Cu(I) atom has a distorted trigonal–planar coordination sphere. The triazapentadienyl ligand acts as a κ(2)-d...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350696/ https://www.ncbi.nlm.nih.gov/pubmed/25844205 http://dx.doi.org/10.1107/S2056989015002169 |