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Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I)

The title complex, [Cu(C(21)H(38)N(5)Si)(C(18)H(15)P)], was obtained from the one-pot reaction between (Dipp)N(Li)SiMe(3) (Dipp = 2,6-diiso­propyl­phen­yl), Me(2)NCN, CuCl and PPh(3). The Cu(I) atom has a distorted trigonal–planar coordination sphere. The tri­aza­penta­dienyl ligand acts as a κ(2)-d...

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Detalles Bibliográficos
Autores principales: Li, Feiguang, Yan, Lei, Tong, Hongbo, Zhou, Meisu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350696/
https://www.ncbi.nlm.nih.gov/pubmed/25844205
http://dx.doi.org/10.1107/S2056989015002169