Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I)

The title complex, [Cu(C(21)H(38)N(5)Si)(C(18)H(15)P)], was obtained from the one-pot reaction between (Dipp)N(Li)SiMe(3) (Dipp = 2,6-diiso­propyl­phen­yl), Me(2)NCN, CuCl and PPh(3). The Cu(I) atom has a distorted trigonal–planar coordination sphere. The tri­aza­penta­dienyl ligand acts as a κ(2)-d...

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Detalles Bibliográficos
Autores principales: Li, Feiguang, Yan, Lei, Tong, Hongbo, Zhou, Meisu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350696/
https://www.ncbi.nlm.nih.gov/pubmed/25844205
http://dx.doi.org/10.1107/S2056989015002169
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author Li, Feiguang
Yan, Lei
Tong, Hongbo
Zhou, Meisu
author_facet Li, Feiguang
Yan, Lei
Tong, Hongbo
Zhou, Meisu
author_sort Li, Feiguang
collection PubMed
description The title complex, [Cu(C(21)H(38)N(5)Si)(C(18)H(15)P)], was obtained from the one-pot reaction between (Dipp)N(Li)SiMe(3) (Dipp = 2,6-diiso­propyl­phen­yl), Me(2)NCN, CuCl and PPh(3). The Cu(I) atom has a distorted trigonal–planar coordination sphere. The tri­aza­penta­dienyl ligand acts as a κ(2)-donor. The N—Cu—N bond angle is 95.88 (14)°. In the tri­aza­penta­dienyl fragment, the C—N bond lengths are in the range 1.328 (5)–1.349 (5) Å, which indicates delocalization of the π-electrons in the NCNCN system.
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spelling pubmed-43506962015-04-03 Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I) Li, Feiguang Yan, Lei Tong, Hongbo Zhou, Meisu Acta Crystallogr E Crystallogr Commun Data Reports The title complex, [Cu(C(21)H(38)N(5)Si)(C(18)H(15)P)], was obtained from the one-pot reaction between (Dipp)N(Li)SiMe(3) (Dipp = 2,6-diiso­propyl­phen­yl), Me(2)NCN, CuCl and PPh(3). The Cu(I) atom has a distorted trigonal–planar coordination sphere. The tri­aza­penta­dienyl ligand acts as a κ(2)-donor. The N—Cu—N bond angle is 95.88 (14)°. In the tri­aza­penta­dienyl fragment, the C—N bond lengths are in the range 1.328 (5)–1.349 (5) Å, which indicates delocalization of the π-electrons in the NCNCN system. International Union of Crystallography 2015-02-07 /pmc/articles/PMC4350696/ /pubmed/25844205 http://dx.doi.org/10.1107/S2056989015002169 Text en © Li et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Li, Feiguang
Yan, Lei
Tong, Hongbo
Zhou, Meisu
Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I)
title Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I)
title_full Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I)
title_fullStr Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I)
title_full_unstemmed Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I)
title_short Crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) N (1),N (5)](tri­phenyl­phosphane-κP)copper(I)
title_sort crystal structure of [1-(2,6-diiso­propyl­phen­yl)-2,4-bis­(di­methyl­amino)-5-tri­methyl­silyl-1,3,5-tri­aza­penta­dienyl-κ(2) n (1),n (5)](tri­phenyl­phosphane-κp)copper(i)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350696/
https://www.ncbi.nlm.nih.gov/pubmed/25844205
http://dx.doi.org/10.1107/S2056989015002169
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