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Crystal structure of {(but-3-en-1-yl)bis­[(pyridin-2-yl)meth­yl]amine-κ(3) N,N′,N′′}di­chlorido­copper(II) diethyl ether hemisolvate

The five-coordinate Cu(II) atom in the title complex [CuCl(2)(C(16)H(19)N(3))]·0.5C(4)H(10)O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu—Cl distance is 0.2626 (6) Å longer than the basal Cu—Cl distance. Weak C—H⋯Cl interactions between pyridine rings and the Cl atoms o...

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Detalles Bibliográficos
Autores principales: Bussey, Katherine A., Connell, Jennifer R., McGlone, Annie R., Mraz, Margaret E., Oshin, Kayode D., Pintauer, Tomislav, Oliver, Allen G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350743/
https://www.ncbi.nlm.nih.gov/pubmed/25844195
http://dx.doi.org/10.1107/S2056989015003448