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Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3) N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate
The five-coordinate Cu(II) atom in the title complex [CuCl(2)(C(16)H(19)N(3))]·0.5C(4)H(10)O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu—Cl distance is 0.2626 (6) Å longer than the basal Cu—Cl distance. Weak C—H⋯Cl interactions between pyridine rings and the Cl atoms o...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350743/ https://www.ncbi.nlm.nih.gov/pubmed/25844195 http://dx.doi.org/10.1107/S2056989015003448 |
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| author | Bussey, Katherine A. Connell, Jennifer R. McGlone, Annie R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Oliver, Allen G. |
| author_facet | Bussey, Katherine A. Connell, Jennifer R. McGlone, Annie R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Oliver, Allen G. |
| author_sort | Bussey, Katherine A. |
| collection | PubMed |
| description | The five-coordinate Cu(II) atom in the title complex [CuCl(2)(C(16)H(19)N(3))]·0.5C(4)H(10)O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu—Cl distance is 0.2626 (6) Å longer than the basal Cu—Cl distance. Weak C—H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions. |
| format | Online Article Text |
| id | pubmed-4350743 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-43507432015-04-03 Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3) N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate Bussey, Katherine A. Connell, Jennifer R. McGlone, Annie R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Oliver, Allen G. Acta Crystallogr E Crystallogr Commun Research Communications The five-coordinate Cu(II) atom in the title complex [CuCl(2)(C(16)H(19)N(3))]·0.5C(4)H(10)O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu—Cl distance is 0.2626 (6) Å longer than the basal Cu—Cl distance. Weak C—H⋯Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions. International Union of Crystallography 2015-02-25 /pmc/articles/PMC4350743/ /pubmed/25844195 http://dx.doi.org/10.1107/S2056989015003448 Text en © Bussey et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Bussey, Katherine A. Connell, Jennifer R. McGlone, Annie R. Mraz, Margaret E. Oshin, Kayode D. Pintauer, Tomislav Oliver, Allen G. Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3) N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate |
| title | Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3)
N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate |
| title_full | Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3)
N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate |
| title_fullStr | Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3)
N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate |
| title_full_unstemmed | Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3)
N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate |
| title_short | Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3)
N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate |
| title_sort | crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ(3)
n,n′,n′′}dichloridocopper(ii) diethyl ether hemisolvate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350743/ https://www.ncbi.nlm.nih.gov/pubmed/25844195 http://dx.doi.org/10.1107/S2056989015003448 |
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