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Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride

The cation of the title compound, [Rh(η(5)-C(5)Me(5))Cl(C(13)H(12)ClN(3))]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinyl­idene­pyridine ligand is non-planar, an angle of 54.42 (7)° being observed between...

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Detalles Bibliográficos
Autores principales: Devika, Neelakandan, Raja, Nandhagopal, Ananthalakshmi, Subbiah, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350752/
https://www.ncbi.nlm.nih.gov/pubmed/25844178
http://dx.doi.org/10.1107/S205698901500184X