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Crystal structure of chlorido(2-{1-[2-(4-chlorophenyl)hydrazin-1-ylidene-κN]ethyl}pyridine-κN)(η(5)-pentamethylcyclopentadienyl)rhodium(III) chloride
The cation of the title compound, [Rh(η(5)-C(5)Me(5))Cl(C(13)H(12)ClN(3))]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinylidenepyridine ligand is non-planar, an angle of 54.42 (7)° being observed between...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350752/ https://www.ncbi.nlm.nih.gov/pubmed/25844178 http://dx.doi.org/10.1107/S205698901500184X |