Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride

The cation of the title compound, [Rh(η(5)-C(5)Me(5))Cl(C(13)H(12)ClN(3))]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinyl­idene­pyridine ligand is non-planar, an angle of 54.42 (7)° being observed between...

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Autores principales: Devika, Neelakandan, Raja, Nandhagopal, Ananthalakshmi, Subbiah, Therrien, Bruno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350752/
https://www.ncbi.nlm.nih.gov/pubmed/25844178
http://dx.doi.org/10.1107/S205698901500184X
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author Devika, Neelakandan
Raja, Nandhagopal
Ananthalakshmi, Subbiah
Therrien, Bruno
author_facet Devika, Neelakandan
Raja, Nandhagopal
Ananthalakshmi, Subbiah
Therrien, Bruno
author_sort Devika, Neelakandan
collection PubMed
description The cation of the title compound, [Rh(η(5)-C(5)Me(5))Cl(C(13)H(12)ClN(3))]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinyl­idene­pyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and the aromatic ring of the [2-(4-chloro­phen­yl)hydrazin-1-yl­idene]ethyl group. In the crystal, a weak inter­ionic N—H⋯Cl hydrogen bond is observed.
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spelling pubmed-43507522015-04-03 Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride Devika, Neelakandan Raja, Nandhagopal Ananthalakshmi, Subbiah Therrien, Bruno Acta Crystallogr E Crystallogr Commun Research Communications The cation of the title compound, [Rh(η(5)-C(5)Me(5))Cl(C(13)H(12)ClN(3))]Cl, adopts a typical piano-stool geometry. The complex is chiral at the metal and crystallizes as a racemate. Upon coordination, the hydrazinyl­idene­pyridine ligand is non-planar, an angle of 54.42 (7)° being observed between the pyridine ring and the aromatic ring of the [2-(4-chloro­phen­yl)hydrazin-1-yl­idene]ethyl group. In the crystal, a weak inter­ionic N—H⋯Cl hydrogen bond is observed. International Union of Crystallography 2015-02-07 /pmc/articles/PMC4350752/ /pubmed/25844178 http://dx.doi.org/10.1107/S205698901500184X Text en © Devika et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Devika, Neelakandan
Raja, Nandhagopal
Ananthalakshmi, Subbiah
Therrien, Bruno
Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride
title Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride
title_full Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride
title_fullStr Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride
title_full_unstemmed Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride
title_short Crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κN]eth­yl}pyridine-κN)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) chloride
title_sort crystal structure of chlorido­(2-{1-[2-(4-chloro­phen­yl)hydrazin-1-yl­idene-κn]eth­yl}pyridine-κn)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(iii) chloride
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350752/
https://www.ncbi.nlm.nih.gov/pubmed/25844178
http://dx.doi.org/10.1107/S205698901500184X
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