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Four-Step Synthesis of the Antimalarial Cardamom Peroxide via an Oxygen Stitching Strategy
[Image: see text] A four-step synthesis of the antimalarial terpene cardamom peroxide, a 1,2-dioxepane-containing natural product, is reported from (−)-myrtenal and molecular oxygen. This highly concise route was guided by biosynthetic logic and enabled by an unusual manganese-catalyzed, tandem hydr...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4353017/ https://www.ncbi.nlm.nih.gov/pubmed/24673099 http://dx.doi.org/10.1021/ja502208z |