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Photophysics of Threaded sp-Carbon Chains: The Polyyne is a Sink for Singlet and Triplet Excitation

[Image: see text] We have used single-crystal X-ray diffraction and time-resolved UV–NIR–IR absorption spectroscopy to gain insights into the structures and excited-state dynamics of a rotaxane consisting of a hexayne chain threaded through a phenanthroline macrocycle and a family of related compoun...

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Detalles Bibliográficos
Autores principales: Movsisyan, Levon D., Peeks, Martin D., Greetham, Gregory M., Towrie, Michael, Thompson, Amber L., Parker, Anthony W., Anderson, Harry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4353026/
https://www.ncbi.nlm.nih.gov/pubmed/25474628
http://dx.doi.org/10.1021/ja510663z