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Photophysics of Threaded sp-Carbon Chains: The Polyyne is a Sink for Singlet and Triplet Excitation
[Image: see text] We have used single-crystal X-ray diffraction and time-resolved UV–NIR–IR absorption spectroscopy to gain insights into the structures and excited-state dynamics of a rotaxane consisting of a hexayne chain threaded through a phenanthroline macrocycle and a family of related compoun...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2014
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4353026/ https://www.ncbi.nlm.nih.gov/pubmed/25474628 http://dx.doi.org/10.1021/ja510663z |