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Preparation of Tetrasubstituted Olefins Using Mono or Double Aerobic Direct C–H Functionalization Strategies: Importance of Steric Effects

[Image: see text] A novel protocol for the synthesis of tetrasubstituted olefins through a biomimetic approach has been explored. Both mono- and diarylations were performed under ambient oxygen pressure, giving a range of highly hindered tetrasubstituted alkenes. For diarylation of disubstituted sub...

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Detalles Bibliográficos
Autores principales: Gigant, Nicolas, Quintin, François, Bäckvall, Jan-E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4354172/
https://www.ncbi.nlm.nih.gov/pubmed/25653084
http://dx.doi.org/10.1021/acs.joc.5b00148