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Emission behaviors of unsymmetrical 1,3-diaryl-β-diketones: A model perfectly disclosing the effect of molecular conformation on luminescence of organic solids
A series of unsymmetrical 1,3-diaryl-β-diketones 1–6 displaying molecular conformation-dependent fluorescence quantum yields have been synthesized. Crystals with planar molecular conformation such as 1, 2, 3 and 4 are highly fluorescent (φ(f): 39–53%), and the one holding slightly twisted conformati...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4360484/ https://www.ncbi.nlm.nih.gov/pubmed/25771808 http://dx.doi.org/10.1038/srep09140 |