Cargando…

Electrochemical selenium- and iodonium-initiated cyclisation of hydroxy-functionalised 1,4-dienes

The cobalt(I)-catalysed 1,4-hydrovinylation reaction of allyloxytrimethylsilane and allyl alcohol with substituted 1,3-dienes leads to hydroxy-functionalised 1,4-dienes in excellent regio- and diastereoselective fashion. Those 1,4-dienols can be converted into tetrahydrofuran and pyran derivatives u...

Descripción completa

Detalles Bibliográficos
Autores principales: Röse, Philipp, Emge, Steffen, Yoshida, Jun-ichi, Hilt, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4361995/
https://www.ncbi.nlm.nih.gov/pubmed/25815067
http://dx.doi.org/10.3762/bjoc.11.18