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Synthesis of dinucleoside acylphosphonites by phosphonodiamidite chemistry and investigation of phosphorus epimerization
The reaction of the diamidite, (iPr(2)N)(2)PH, with acyl chlorides proceeds with the loss of HCl to give the corresponding acyl diamidites, RC(O)P(N(iPr)(2))(2) (R = Me (7), Ph (9)), without the intervention of sodium to give a phosphorus anion. The structure of 9 was confirmed by single-crystal X-r...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4362088/ https://www.ncbi.nlm.nih.gov/pubmed/25815068 http://dx.doi.org/10.3762/bjoc.11.19 |