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Acetic Acid Mediated Synthesis of Phosphonate-Substituted Titanium Oxo Clusters

New phosphonate/acetate-substituted titanium oxo/alkoxo clusters were prepared from Ti(OiPr)(4) and bis(trimethylsilyl) phosphonates in the presence of acetic acid, which served to generate water in situ through ester formation. The process led to clusters with a higher degree of condensation than i...

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Detalles Bibliográficos
Autores principales: Czakler, Matthias, Artner, Christine, Schubert, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4362471/
https://www.ncbi.nlm.nih.gov/pubmed/25814832
http://dx.doi.org/10.1002/ejic.201400051