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Crystal structures and conformations of two Diels–Alder adduct derivatives: 1,8-bis(thiophen-2-yl)-14-oxatetracyclo[6.5.1.0(2,7).0(9,13)]tetradeca-2(7),3,5-trien-10-one and 1,8-diphenyl-14-oxatetracyclo[6.5.1.0(2,7).0(9,13)] tetradeca-2,4,6-trien-10-one
The title compounds, C(21)H(16)O(2)S(2) (I) and C(25)H(20)O(2) (II), are products of a tandem ‘pincer’ Diels–Alder reaction consisting of [2 + 2] cycloadditions between benzo[c]furan and cyclopentanone. Each comprises a fused tetracyclic ring system containing two five-membered rings (in envelop...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384542/ https://www.ncbi.nlm.nih.gov/pubmed/25878822 http://dx.doi.org/10.1107/S2056989015001073 |