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Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation

The concept of aromaticity has long played an important role in chemistry and continues to fascinate both experimentalists and theoreticians. Among the archetypal aromatic compounds, heteroaromatics are particularly attractive. Recently, substitution of a transition-metal fragment for a carbon atom...

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Detalles Bibliográficos
Autores principales: Wang, Tongdao, Han, Feifei, Huang, Haiping, Li, Jinhua, Zhang, Hong, Zhu, Jun, Lin, Zhenyang, Xia, Haiping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4391318/
https://www.ncbi.nlm.nih.gov/pubmed/25856747
http://dx.doi.org/10.1038/srep09584