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Zero-strain reductive intercalation in a molecular framework
Reductive intercalation of potassium within the molecular framework Ag(3)[Fe(CN)(6)] gives rise to a volume strain that is an order of magnitude smaller than is typical for common ion-storage materials. We suggest that framework flexibility might be exploited as a general strategy for reducing cycli...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4396389/ https://www.ncbi.nlm.nih.gov/pubmed/25892969 http://dx.doi.org/10.1039/c4ce02364a |