Zero-strain reductive intercalation in a molecular framework

Reductive intercalation of potassium within the molecular framework Ag(3)[Fe(CN)(6)] gives rise to a volume strain that is an order of magnitude smaller than is typical for common ion-storage materials. We suggest that framework flexibility might be exploited as a general strategy for reducing cycli...

Descripción completa

Detalles Bibliográficos
Autores principales: Hill, Joshua A., Cairns, Andrew B., Lim, Jared J. K., Cassidy, Simon J., Clarke, Simon J., Goodwin, Andrew L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4396389/
https://www.ncbi.nlm.nih.gov/pubmed/25892969
http://dx.doi.org/10.1039/c4ce02364a
Descripción
Sumario:Reductive intercalation of potassium within the molecular framework Ag(3)[Fe(CN)(6)] gives rise to a volume strain that is an order of magnitude smaller than is typical for common ion-storage materials. We suggest that framework flexibility might be exploited as a general strategy for reducing cycling strain in battery and ion-storage materials.

Ejemplares similares